WebMay 27, 2024 · Chiral MOF-74 materials were synthesised by post-synthetic modification by using proline as chiral inductor. Combined experimental and theoretical studies show that proline coordinates monodentate to the Zn 2+ within the metal–organic framework (MOF). Along with introducing chiral features, defects are formed in the MOF-74 topology. WebJun 25, 2024 · Particularly, the Ca-based MOF 1 with 2,4,6-trimethyl groups at the substituents exhibited enhanced catalytic performance, affording the highest enantioselectivity (up to 97%). It is also the first report of the heterogeneous catalyst with chiral non-noble metal phosphonate active sites for asymmetric transfer hydrogenation …
Chiral Metal–Organic Frameworks Chemical Reviews
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